简介
"...Peter C. Vollhardt's Organic Chemistry wins hands down ...the book is visually appealing, up-to-date and it is informative and easy to follow." Nature on the Second Edition Organic Chemistry, 3/e combines the features of successful earlier editions with new material and new pedagogical aids. The authors cover structure before function, introducing stereochemistry and spectroscopy early on, and the text is loaded with wide-ranging applications from the biological and environmental sciences and other disciplines. The emphasis is on the most important reactions and on helping students develop synthetic strategy techniques for exploring chemical structures. New features include more on acid-base chemistry, new discussions of stereoscopic techniques and 20% more problems, with the addition of new-style Team and Pre-professional Problems. A CD-ROM with animations, simulations and exercises is packaged with the book. Organic Chemistry 3.0 CD-ROM 7 Animations and simulations (e.g. numerous Reaction Mechanisms, Conformational Analysis, and Stereochemistry) 7 Molecular Viewing Program containing all molecules in the text 7 Spectroscopy interpretation and NMR exercise 7 Q & A with feedback and references 7 Progressive Reveal Solutions (Check Answer, Give Hint, Show Me) for selected problems in the text 7 Electronic flash cards, glossary and periodic table. All figures from the text. 7 Expansion Modules (Emphasis: industrial applications) 7 Presentation Manager
目录
Table Of Contents:
Preface: A User's Guide to "Organic Chemistry: Structure and Function" xxiii(11)
About the Authors xxxiv
1 Structure and Bonding in Organic Molecules 1(50)
2 Alkanes Molecules Lacking Functional Groups 51(42)
3 Reactions of Alkanes Bond-Dissociation Energies, Radical Halogenation, and Relative Reactivity 93(36)
4 Cyclic Alkanes 129(36)
5 Stereoisomers 165(46)
6 Properties and Reactions of Haloalkanes Bimolecular Nucleophilic Substitution 211(36)
7 Further Reactions of Haloalkanes Unimolecular Substitution and Pathways of Elimination 247(36)
8 Hydroxy Functional Group Properties of the Alcohols and Strategy in Synthesis 283(47)
9 Further Reactions of Alcohols and the Chemistry of Ethers 330(54)
10 Using Nuclear Magnetic Resonance Spectroscopy to Deduce Structure 384(54)
11 Alkenes and Infrared Spectroscopy 438(45)
12 Reactions of Alkenes 438(60)
13 Alkynes The Carbon-Carbon Triple Bond 543(40)
14 Delocalized Pi Systems Investigation by Ultraviolet and Visible Spectroscopy 583(54)
15 Unusual Stability of the Cyclic Electron Sextet Benezene, Other Cyclic Polyenes, and Electrophilic Aromatic Substitution 637(52)
16 Electrophilic Attack on Derivatives of Benzene Substituents Control Regioselectivity 689(39)
17 Aldehydes and Ketones The Carbony1 Group 728(52)
18 Enols and Enones Alpha, Beta-Unsaturated Alcohols, Aldeyhydes, and Ketones 780(45)
19 Carboxylic Acids 825(53)
20 Carboxylic Acid Derivatives and Mass Spectrometry 878(58)
21 Amines and Their Derivatives Functional Groups Containing Nitrogen 936(46)
22 Chemistry of Benzene Substituents Alkylbenzenes, Phenols, and Benzenamines 982(55)
23 Ester Enolates and Acyl Anion Equivalents Syntheses of Bita-Dicarbony1 and Alpha-Hydroxycarbony1 Compounds 1037(31)
24 Carbohydrates Polyfunctional Compounds in Nature 1068(48)
25 Heterocycles Heteroatoms in Cyclic Organic Compounds 1116(40)
26 Amino Acids, Peptides, proteins, and Nucleic Acids Nitrogen-Containing Polymers in Nature 1156
Answers to Exercises
Index
Preface: A User's Guide to "Organic Chemistry: Structure and Function" xxiii(11)
About the Authors xxxiv
1 Structure and Bonding in Organic Molecules 1(50)
2 Alkanes Molecules Lacking Functional Groups 51(42)
3 Reactions of Alkanes Bond-Dissociation Energies, Radical Halogenation, and Relative Reactivity 93(36)
4 Cyclic Alkanes 129(36)
5 Stereoisomers 165(46)
6 Properties and Reactions of Haloalkanes Bimolecular Nucleophilic Substitution 211(36)
7 Further Reactions of Haloalkanes Unimolecular Substitution and Pathways of Elimination 247(36)
8 Hydroxy Functional Group Properties of the Alcohols and Strategy in Synthesis 283(47)
9 Further Reactions of Alcohols and the Chemistry of Ethers 330(54)
10 Using Nuclear Magnetic Resonance Spectroscopy to Deduce Structure 384(54)
11 Alkenes and Infrared Spectroscopy 438(45)
12 Reactions of Alkenes 438(60)
13 Alkynes The Carbon-Carbon Triple Bond 543(40)
14 Delocalized Pi Systems Investigation by Ultraviolet and Visible Spectroscopy 583(54)
15 Unusual Stability of the Cyclic Electron Sextet Benezene, Other Cyclic Polyenes, and Electrophilic Aromatic Substitution 637(52)
16 Electrophilic Attack on Derivatives of Benzene Substituents Control Regioselectivity 689(39)
17 Aldehydes and Ketones The Carbony1 Group 728(52)
18 Enols and Enones Alpha, Beta-Unsaturated Alcohols, Aldeyhydes, and Ketones 780(45)
19 Carboxylic Acids 825(53)
20 Carboxylic Acid Derivatives and Mass Spectrometry 878(58)
21 Amines and Their Derivatives Functional Groups Containing Nitrogen 936(46)
22 Chemistry of Benzene Substituents Alkylbenzenes, Phenols, and Benzenamines 982(55)
23 Ester Enolates and Acyl Anion Equivalents Syntheses of Bita-Dicarbony1 and Alpha-Hydroxycarbony1 Compounds 1037(31)
24 Carbohydrates Polyfunctional Compounds in Nature 1068(48)
25 Heterocycles Heteroatoms in Cyclic Organic Compounds 1116(40)
26 Amino Acids, Peptides, proteins, and Nucleic Acids Nitrogen-Containing Polymers in Nature 1156
Answers to Exercises
Index
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