Preface to the First Edition p. ix
Preface to the Third Edition p. xi
To the Instructor p. xiii
Interactive Chemical Process Principles p. xv
Nomenclature p. xvii
Glossary p. xx
Engineering Problem Analysis p. 1
What Some Chemical Engineers Do for a Living p. 3
Introduction to Engineering Calculations p. 7
Instructional Objectives p. 7
Units and Dimensions p. 8
Conversion of Units p. 9
Systems of Units p. 10
Force and Weight p. 12
Numerical Calculation and Estimation p. 13
Dimensional Homogeneity and Dimensionless Quantities p. 20
Process Data Representation and Analysis p. 22
Summary p. 30
Problems p. 31
Processes and Process Variables p. 42
Instructional Objectives p. 43
Mass and Volume p. 43
Flow Rate p. 45
Chemical Composition p. 47
Pressure p. 54
Temperature p. 60
Summary p. 63
Problems p. 65
Material Balances p. 81
Fundamentals of Material Balances p. 83
Instructional Objectives p. 83
Process Classification p. 84
Balances p. 85
Material Balance Calculations p. 89
Balances on Multiple-Unit Processes p. 104
Recycle and Bypass p. 110
Chemical Reaction Stoichiometry p. 116
Balances on Reactive Processes p. 125
Combustion Reactions p. 142
Some Additional Considerations about Chemical Processes p. 151
Summary p. 153
Problems p. 155
Single-Phase Systems p. 187
Instructional Objectives p. 188
Liquid and Solid Densities p. 189
Ideal Gases p. 191
Equations of State for Nonideal Gases p. 199
The Compressibility Factor Equation of State p. 206
Summary p. 213
Problems p. 214
Multiphase Systems p. 237
Instructional Objectives p. 239
Single-Component Phase Equilibrium p. 240
The Gibbs Phase Rule p. 247
Gas-Liquid Systems: One Condensable Component p. 249
Multicomponent Gas-Liquid Systems p. 255
Solutions of Solids in Liquids p. 264
Equilibrium Between Two Liquid Phases p. 271
Adsorption on Solid Surfaces p. 275
Summary p. 278
Problems p. 280
Energy Balances p. 311
Energy and Energy Balances p. 313
Instructional Objectives p. 314
Forms of Energy: The First Law of Thermodynamics p. 315
Kinetic and Potential Energy p. 317
Energy Balances on Closed Systems p. 318
Energy Balances on Open Systems at Steady State p. 320
Tables of Thermodynamic Data p. 325
Energy Balance Procedures p. 329
Mechanical Energy Balances p. 333
Summary p. 337
Problems p. 340
Balances on Nonreactive Processes p. 357
Instructional Objectives p. 357
Elements of Energy Balance Calculations p. 358
Changes in Pressure at Constant Temperature p. 365
Changes in Temperature p. 366
Phase Change Operations p. 377
Mixing and Solution p. 395
Summary p. 406
Problems p. 409
Balances on Reactive Processes p. 440
Instructional Objectives p. 441
Heats of Reaction p. 442
Measurement and Calculation of Heats of Reaction: Hess's Law p. 445
Formation Reactions and Heats of Formation p. 447
Heats of Combustion p. 448
Energy Balances on Reactive Processes p. 450
Fuels and Combustion p. 464
Summary p. 473
Problems p. 475
Computer-Aided Balance Calculations p. 504
Instructional Objectives p. 504
Degree-of-Freedom Analysis Revisited p. 504
Sequential Modular Simulation p. 511
Equation-Based Simulation p. 522
Commercial Process Simulation Packages p. 533
Final Considerations p. 533
Problems p. 534
Balances on Transient Processes p. 543
Instructional Objectives p. 543
The General Balance Equation...Again p. 544
Material Balances p. 548
Energy Balances on Single-Phase Nonreactive Processes p. 554
Simultaneous Transient Balances p. 560
Summary p. 563
Problems p. 564
Case Studies p. 577
Production of Chlorinated Polyvinyl Chloride p. 579
PVC Chlorination Reaction Chemistry p. 580
Process Description p. 581
Problems p. 584
Steam Reforming of Natural Gas and Subsequent Synthesis of Methanol p. 591
Process Description p. 592
Problems p. 595
Scrubbing of Sulfur Dioxide from Power Plant Stack Gases p. 607
Process Description p. 603
Problems p. 605
Computational Techniques p. 607
The Method of Least Squares p. 607
Iterative Solution of Nonlinear Algebraic Equations p. 610
Numerical Integration p. 622
Physical Property Tables p. 627
Selected Physical Property Data p. 628
Heat Capacities p. 635
Vapor Pressure of Water p. 638
Antoine Equation Constants p. 640
Properties of Saturated Steam: Temperature Table p. 642
Properties of Saturated Steam: Pressure Table p. 644
Properties of Superheated Steam p. 650
Specific Enthalpies of Selected Gases: SI Units p. 652
Specific Enthalpies of Selected Gases: American Engineering Units p. 652
Atomic Heat Capacities for Kopp's Rule p. 653
Integral Heats of Solution and Mixing at 25[degree]C p. 653
Answers to Test Yourselves p. 655
Answers to Selected Problems p. 665
Index p. 669