简介
Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors.
Transition Metals in Supramolecular Chemistryfocuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.
目录
Preface
Organizing Committee
List of Participants and Observers
Supramolecular photochemistry and photophysics. Energy-conversion and information-processing devices based on transition metal complexes p. 1
Transition metal redox active ligand systems for recognising cationic and anionic guest species p. 33
Ligand design for enhanced molecular organization - selectivity and specific sequencing in multiple receptor ligands, and orderly molecular entanglements p. 55
Metal ions: a self-assembly motif in supramolecular oligomers p. 81
Biomedical targeting: a role for supramolecular chemistry p. 101
Redox chemistry of metal ion complexes: preparation of new materials p. 115
pH and redox switches based on metal centres p. 133
Schiff base macrocycles and metallo-biosite modelling p. 153
Self-assembly of mono- and dinuclear metal complexes; oxidation catalysis and metalloenzyme models p. 171
Artificial porphyrins containing cyclopropane units functioning as electron shuttles p. 191
Homo- and heterobinuclear metal complexes with bis-macrocyclic ligands p. 211
Ferrocene as a building block for supramolecular chemistry systems p. 227
Macrocyclic polyamine complexes beyond metalloenzyme models p. 245
Towards molecular wires and switches: exploiting coordination chemistry for non-linear optics and molecular electronics p. 261
Molecular interactions between metalloproteins involved in electron transfer processes: tetraheme cytochrome c[subscript 3] and flavodoxin. NMR and molecular modeling studies p. 279
Supramolecular models of metallo-proteins p. 291
The role of macrocyclic receptors in organization of metal centres p. 309
Metallomacrocycles and -clefts: receptors for neutral molecules and anions p. 329
Chiral recognition by functionalized cyclodextrin metal complexes p. 351
Transition metal-directed threading and knotting processes p. 371
Expanded porphyrins. Receptors for cationic, anionic and neutral substrates p. 391
Following the self-assembly process in solution p. 409
Author Index p. 425
Subject Index p. 427
Organizing Committee
List of Participants and Observers
Supramolecular photochemistry and photophysics. Energy-conversion and information-processing devices based on transition metal complexes p. 1
Transition metal redox active ligand systems for recognising cationic and anionic guest species p. 33
Ligand design for enhanced molecular organization - selectivity and specific sequencing in multiple receptor ligands, and orderly molecular entanglements p. 55
Metal ions: a self-assembly motif in supramolecular oligomers p. 81
Biomedical targeting: a role for supramolecular chemistry p. 101
Redox chemistry of metal ion complexes: preparation of new materials p. 115
pH and redox switches based on metal centres p. 133
Schiff base macrocycles and metallo-biosite modelling p. 153
Self-assembly of mono- and dinuclear metal complexes; oxidation catalysis and metalloenzyme models p. 171
Artificial porphyrins containing cyclopropane units functioning as electron shuttles p. 191
Homo- and heterobinuclear metal complexes with bis-macrocyclic ligands p. 211
Ferrocene as a building block for supramolecular chemistry systems p. 227
Macrocyclic polyamine complexes beyond metalloenzyme models p. 245
Towards molecular wires and switches: exploiting coordination chemistry for non-linear optics and molecular electronics p. 261
Molecular interactions between metalloproteins involved in electron transfer processes: tetraheme cytochrome c[subscript 3] and flavodoxin. NMR and molecular modeling studies p. 279
Supramolecular models of metallo-proteins p. 291
The role of macrocyclic receptors in organization of metal centres p. 309
Metallomacrocycles and -clefts: receptors for neutral molecules and anions p. 329
Chiral recognition by functionalized cyclodextrin metal complexes p. 351
Transition metal-directed threading and knotting processes p. 371
Expanded porphyrins. Receptors for cationic, anionic and neutral substrates p. 391
Following the self-assembly process in solution p. 409
Author Index p. 425
Subject Index p. 427
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