基础化学实验（中、英文，第3版）

第一部分  基础化学实验基本知识第一章  实验室规则及安全知识1.基础化学实验目的2.化学实验室一般规则3.化学实验室的安全知识4.化学实验操作过程中可能发生的事故与处理5.化学实验室的防火与灭火常识第二章  基础化学实验常用仪器1.实验室常用玻璃仪器1.1  玻璃仪器的洗涤1.2  玻璃仪器的干燥2.容量分析仪器2.1  滴定管2.2  容量瓶2.3  移液管和吸量管3.常用定量分析仪器3.1  分析天平3.2  pH计3.3  721型分光光度计3.4  FM-9X型冰点渗透压计3.5  离心机第三章  实验结果的表示1.实验误差与有效数字1.1  实验误差1.2  准确度和精密度1.3  有效数字2.实验数据的处理2.1  列表法2.2  作图法2.3  计算机处理3.实验报告第二部分  基础化学实验课题实验课题一  基本操作训练实验实验一  常用容量分析仪器操作练习实验二  分析天平称量练习实验三  缓冲溶液的配制和性质、溶液pH测量实验四  胶体溶液的制备与性质实验课题二  滴定分析实验实验五  酸碱滴定分析法1.标准盐酸溶液浓度的标定2.标准氢氧化钠溶液浓度的标定3.草酸纯度的测定4.硼砂含量的测定5.返滴定法测定阿司匹林的含量实验六  氧化还原滴定法1.高锰酸钾法2.碘量法实验七  配位滴定分析1.水的硬度的测定2.明矾含量的测定3.葡萄糖酸钙含量的测定实验课题三  分光光度法实验实验八  分光光度法测定水样中铁含量1.邻二氮菲法2.硫氰酸盐法3.磺基水杨酸法实验九  分光光度法测定阿司匹林药片的含量实验十  分光光度法测定磺基水杨酸合铁的组成和稳定常数实验十一  荧光分析法测定维生素B2的含量实验十二  紫外分光光度法对维生素B12的鉴别与含量测定实验课题四  化学原理实验实验十三  稀溶液的依数性及其应用1.凝固点降低法测定溶质的相对分子质量2.利用溶液的渗透浓度测定溶质的相对分子质量3.冰点渗透压计的应用实验十四  置换法测定镁的原子量实验十五  化学反应速率与活化能的测定实验课题五  化合物制备实验实验十六  氯化钠的精制实验十七  硫酸亚铁铵的制备实验课题六  综合及研究实验实验十八  醋酸解离平衡常数的测定与市售食醋中HAc含量的测定实验十九  茶叶中钙、镁和铁含量的综合测定实验课题七  自行设计实验实验二十  设计及研究Part Ⅰ   Experiment Essentials in Basic ChemistryChapter 1  Laboratory Rules and Safety Information1. The Purpose of Experiments in Basic Chemistry2. General Rules in Laboratory3. Safety Information4. The Treatment of Accidents in Chemical Experiments5. Fire Prevention and Extinguishing KnowledgeChapter 2  Ordinary Instruments in Chemical Experiments1. Ordinary Glassware in Chemical Lab1.1  Cleaning Glassware1.2  Drying Glassware2. Volumetric Glassware2.1   Burets2.2  Volumetric Flasks2.3  Pipets3. Analytical Instruments3.1   Analytical Balance3.2  pH Meter3.3  721-Speetrophotometer3.4  FM-9X Osmometer3.5  CentrifugesChapter 3  Experiment Results and their Expressions1. Experimental Error and Significant Figures1.1  Experimental Error1.2  Accuracy and Precision1.3  Significant Figures2. Treatments of Experimental Data2.1  Tabling2.2  Graphing2.3  Computer treatment3. Experiment ReportsPart Ⅱ  Experiments in Basic ChemistryChapter 1  Basic Practice Experiments of OperationExperiment 1  Operation of Volumetric AnalysisExperiment 2  Weighing Practice of Analytical BalanceExperiment 3  Preparation and Properties of Buffers and Measure the pH of the SolutionExperiment 4  Preparation and Properties of Colloidal SystemsChapter 2  Experiments of TitrationExperiment 5  Acid-Base Titration Analysis1. The Standardization of HC1 Solution Concentration2. The Standardization of the Concentration of NaOH3. Determination of Purity of Oxalic Acid4. Determination of Content of Borax5. Determination of Aspirin by Back TitrationExperiment 6  Oxidation-Reduction Titration1. Potassium permanganate method2. IodimetryExperiment 7  Complexometric Titration1. Determination of the Hardness of Water2. Determination Content of KAI(SO4)2·12H20 in Alum3. Determination of calcium gluconateChapter 3  SpectrophotometryExperiment 8  Determination of the Content of Fe3 + ( Fe2+) in Water Sample with Spectrophotometry1. O-phenanthroline Method2. Sulfocyan (MSCN) Method3. Sulfosalicylic Acid MethodExperiment 9  Determination of the Content of Aspirin in Tablets by Visible SpectrophotometryExperiment 10  Determination of the Formula and the Stability Constant for a sulfosalicylate Iron ( 11I ) Complex by SpectrophotometryExperiment 11  Determination of the Content of Vitamin B2 by Fluorescence SpectrophotometryExperiment 12  Identification and Determination of Vitamin B12 with Ultraviolet SpectrophotometryChapter 4  Chemical Principle ExperimentsExperiment 13  Colligative Properties of Dilute Solution and Their Application1. Determination of Molar Mass of Glucose by Freezing Point Depression2. Determination of the Molar Mass of Glucose by Determining Osmolarity3. Application of Freezing Point OsmometerExperiment 14  Determination of the Atomic Mass of Magnesium by Replacement ReactionExperiment 15  Determination of the Rate of Chemical Reaction and Activation EnergyChapter 5  Preparation of CompoundsExperiment 16  Refining Sodium ChlorideExperiment 17  Preparation of Ammonium Iron (Ⅱ) SulfateChapter 6  Comprehensive ExperimentsExperiment 18  Determination of Dissociation Equilibrium Constant of Acetic Acid and Content of HAc in Commercial VinegarExperiment 19  Comprehensive Determinations of Content of Ca,Mg and Fe in TeaChapter 7  Self-Designed ExperimentExperiment 20  Design and Research附录Ⅰ  国际相对原子量表附录Ⅱ  不同温度下水的饱和蒸汽压．附录Ⅲ  危险药品的分类、性质和管理一、危险药品二、剧毒物品三、化学实验室毒品管理规定附录Ⅳ  标准缓冲溶液附录Ⅴ  参考书目