简介
Researchers in catalysis and surface science will find this book to be an invaluable compendium of material on the preparation, characterization, and investigation of model catalyst systems, including single sites, supported and unsupported clusters, and single crystals of metal, metal alloys, and metal oxides. The connections made between heterogeneous and homogeneous catalysis are particularly welcome. --Alexis T. Bell, Department of Chemical Engineering, University of California, Berkeley This is a superb collection of papers covering the latest developments in the use of models in fundamental catalytic science. It is a valuable addition to the libraries of those interested in the fundamentals of surface-catalyzed reactions. --D. Wayne Goodman, Department of Chemistry, Texas A&M University This is a comprehensive collection of the development of surface science over the last four decades. The book proves that the era of oversimplified model systems is over; the dynamics of materials and reactions is now accessible for rigorous experimental and theoretical study. The book is an invaluable, authoritative source of information both for the surface scientist and the catalysis practitioner. --Robert Schl枚gl, Department of Inorganic Chemistry, Fritz-Haber-Institute of the Max-Planck-Society, Berlin, Germany This book is an important resource for anyone interested in the latest advances in catalysis. It contains contributions from leaders in the field, and addresses issues related to mechanism, characterization, and selectivity. A wide range of new catalyst design principles is introduced, within the context of chiral surfaces for enantioselective reactions, novel catalyst compositions and structures, well-defined, single site catalytic centers, and the influence of nanostructures on catalytic performance. --T. Don Tilley, Department of Chemistry, University of California, Berkeley
目录
Foreword 4
Preface 8
Contents 10
Contributors 13
Chapter 1 Catalytic Chemistry of Hydrocarbon Conversion Reactions on Metallic Single Crystals 18
Chapter 2 Structure, Characterization and Reactivity of Pt\u2013Sn Surface Alloys 46
Chapter 3 Catalysis at Bimetallic Electrochemical Interfaces 68
Chapter 4 Enantioselectivity on Naturally Chiral Metal Surfaces 91
Chapter 5 Chiral Expression by Organic Architectures at Metal Surfaces: the Role of Both Adsorbate and Surface in Inducing Asymmetry 112
Chapter 6 Role of C and P Sites on the Chemical Activity of Metal Carbides and Phosphides: From Clusters to Single-Crystal Surfaces 131
Chapter 7 Surface Reactions of Oxygen Containing Compounds on Metal Oxide (TiO2 and UO2) Single Crystals 147
Chapter 8 Surface Science Studies of Strong Metal-Oxide Interactions on Model Catalysts 169
Chapter 9 Surface Thermodynamics: Small Molecule Adsorption Calorimetry on Metal Single Crystals 188
Chapter 10 Surface Femtochemistry 215
Chapter 11 The Incorporation of Added Metal Atoms into Structures of Reaction Intermediates on Catalytic Metal Surfaces 234
Chapter 12 Chemical Bonding on Metal Surfaces 263
Chapter 13 From Molecular Insights to Novel Catalysts Formulation 285
Chapter 14 The Reactivity of Gas-Phase Metal Oxide Clusters: Systems for Understanding the Mechanisms of Heterogeneous Catalysts 303
Chapter 15 Catalysis by Noble Metal Nanoparticles Supported on Thin-Oxide Films 328
Chapter 16 Catalysis by Supported Size-Selected Clusters 353
Chapter 17 Catalysis by Thin Oxide Films and Oxide Nanoparticles 374
Chapter 18 Catalysis with Transition Metal Nanoparticles in Colloidal Solution: Heterogeneous or Homogeneous? 402
Chapter 19 Well-Defined Metallic and Bimetallic Clusters Supported on Oxides and Zeolites 422
Chapter 20 A Convergence of Homogeneous and Heterogeneous Catalysis: Immobilized Organometallic Catalysts 447
Chapter 21 Single-Site Heterogeneous Catalysts: Innovations, Advantages, and Future Potential in Green Chemistry and Sustainable Technology 462
Chapter 22 Molecular-Imprinted Metal Complexes for the Design of Catalytic Structures 480
Chapter 23 Heterogeneous Catalyst Design by Multiple Functional Group Positioning in Organic\u2013Inorganic Materials: On the Route to Analogs of Multifunctional Enzymes 499
Index 521
Preface 8
Contents 10
Contributors 13
Chapter 1 Catalytic Chemistry of Hydrocarbon Conversion Reactions on Metallic Single Crystals 18
Chapter 2 Structure, Characterization and Reactivity of Pt\u2013Sn Surface Alloys 46
Chapter 3 Catalysis at Bimetallic Electrochemical Interfaces 68
Chapter 4 Enantioselectivity on Naturally Chiral Metal Surfaces 91
Chapter 5 Chiral Expression by Organic Architectures at Metal Surfaces: the Role of Both Adsorbate and Surface in Inducing Asymmetry 112
Chapter 6 Role of C and P Sites on the Chemical Activity of Metal Carbides and Phosphides: From Clusters to Single-Crystal Surfaces 131
Chapter 7 Surface Reactions of Oxygen Containing Compounds on Metal Oxide (TiO2 and UO2) Single Crystals 147
Chapter 8 Surface Science Studies of Strong Metal-Oxide Interactions on Model Catalysts 169
Chapter 9 Surface Thermodynamics: Small Molecule Adsorption Calorimetry on Metal Single Crystals 188
Chapter 10 Surface Femtochemistry 215
Chapter 11 The Incorporation of Added Metal Atoms into Structures of Reaction Intermediates on Catalytic Metal Surfaces 234
Chapter 12 Chemical Bonding on Metal Surfaces 263
Chapter 13 From Molecular Insights to Novel Catalysts Formulation 285
Chapter 14 The Reactivity of Gas-Phase Metal Oxide Clusters: Systems for Understanding the Mechanisms of Heterogeneous Catalysts 303
Chapter 15 Catalysis by Noble Metal Nanoparticles Supported on Thin-Oxide Films 328
Chapter 16 Catalysis by Supported Size-Selected Clusters 353
Chapter 17 Catalysis by Thin Oxide Films and Oxide Nanoparticles 374
Chapter 18 Catalysis with Transition Metal Nanoparticles in Colloidal Solution: Heterogeneous or Homogeneous? 402
Chapter 19 Well-Defined Metallic and Bimetallic Clusters Supported on Oxides and Zeolites 422
Chapter 20 A Convergence of Homogeneous and Heterogeneous Catalysis: Immobilized Organometallic Catalysts 447
Chapter 21 Single-Site Heterogeneous Catalysts: Innovations, Advantages, and Future Potential in Green Chemistry and Sustainable Technology 462
Chapter 22 Molecular-Imprinted Metal Complexes for the Design of Catalytic Structures 480
Chapter 23 Heterogeneous Catalyst Design by Multiple Functional Group Positioning in Organic\u2013Inorganic Materials: On the Route to Analogs of Multifunctional Enzymes 499
Index 521
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