CHAPTER 1. STABILIZATION AND MODIFICATION OF CELLULOSE
DIACETATE
Ii. Modern state of investigations of photochemical destruction of CDA.......
1.2. About the mechanism of photooxidative destruction of cellulose
acetate. ... .. .. .. . ... .. . . . .. .. .9 . . .... ... . .. .. . . . . ..... .. . 8
1.3. Kinetics of radicals accumulation ... .... .. . ....,... . .. .. ,.... .. I1
1 4. Kinetic regularities of CDA photooxidation..... ............................... 16
1 .5. Light-stabilization of CDA by hexaazocyclanes .................... ...........
1.6. Light stabilization of CDA by polyconjugated azomethine compounds........... 27
1.7. Light-stabilization of CDA by nitrogen- and sulphur- containing aromatic
compounds.. .......... ... ...... .......,,.... . ..... .......... 46
1.8. Stabilization by means of chemical modification of CDA ............... .......... 49
1.9. Thermo- and photooxidative destruction of dyed polyvinyl-alcohol fibres......52
CHAP ER 2. STABILIZATION AND MODIFICATION OF POLYCAPROAMIDE
2.1. Photo- and thermal destruction of aliphatic polyamides ...................... 62
2.1 . 1. Sensitized photooxidation of polyamides...................... .......63
2.1.2. Photooxidation of dyed aliphatic polyamides ..... . .... . .............65
2, .3. Thermnooxidative destruction of polyamides....._..............................66
2.1.4. Photostabilization of polyamides ....... ....................... ...67
2. 1,5 Polymer dyeing in triass ........... ....... ......... ......... ..... 71
2.1..6. Derivatives of aroilenebenzimidazoles as dyes for polyamides dyeing
in mass. ...................... ...........4
2 32. Photooxidative destruction of dyed PCA...... ,,.,..... .... ............ _..82
2.3. Physico-mechanical characteristics of stabilized PCA-fibres at
photooxidation...... . . ............. _....... .......... .. . 84
2.4. Effect of derivatives of bis-aroilenebenzimidazoles on supermolecular
structure of PCA........ .... ............. ....... ......... ..85
2.5. Mechanism of light-stabilizing action of bis-aroilenebenzimidazoles.. .........88
2.5.1. Absorption of oxygen by polycaproamide stabilized
by aroilenbenzimidazole derivatives ... ,..,..._. ...._ .................. 88
2.(6 Spectral-luminescent investigations of PCA, containing
additives of bis-aroilenebenzimidazoles .................;.. 93
2.6,1 Spectral-luminescent properties of PCA .................... ..............93
2.6.2. Spectral-luminescent properties of stabilized PCA.... .. ...... ......... __95
2.7, Effect of long-wave irradiation on dyed PCA-fibre...... ........ .......... 98
2.8 Thermnnooxidative destruction of modified PCA....................... ..... 100
CHAPTER STABILIZATION AND MODIFICAION OF POLYETHYL-
ENEREPHTHALATE
3.1. Photo-and photooxidative destruction of PETP. . L ...... 1
3.2. Methods of PETP modification ... . l16..........-... 13
3 3 Modification of PETP by additives of poyfuntiona action... 119
3.4. Modfication of PETP by hexaazocyclanes .. 12
3.5. Themeo and thermooxidative destruction of modified PETP-fibre ... . _135
3.6. Light-stabilization of polyesters by hexaazocyclanes......_ :: ...... ... 162